Digitalfire Ceramics Technical Articles

The Four Levels on Which to View Ceramic Glazes

Section: Glazes, Subsection: Introduction

Description

By knowing which level to view a glaze from you are much better equipped to understand and control it. The levels are process, recipe, material, oxide.

Article

Glazing is perhaps the most difficult aspect of ceramics and the one for which you bear the most accountability (for design,  functionality, and safety). It is important to know 'why' glazes do what they do. It is better to 'understand' and control a few glazes than struggle with many that end up controlling you. Watch out for the dragon who seems innocent at first. The traffic in glaze recipes and the trend toward abdicating control to suppliers and consultants, these mentalities breed ignorance and invite trouble. The answer is to formulate your own glazes.

To understand the complexities of glazes one must marshal several different viewpoints, that is, understand things on different levels. There is usually no one simple answer for formulating or fixing a glaze. We recommend you develop the ability to determine which level is most closely related to the problem at hand. Study the trouble shooting articles at the bottom on this page and note how thinking in terms of these four levels helps to formulate questions that lead to solutions.

• The Process Level

  The technician immerses himself in understanding the equipment used to apply, dry, decorate, fire, and cool the ware. By fine tuning these devices he exercises considerable control over standard plant or studio recipes or glazes purchased ready made from suppliers. When problems arise he/she analyses them mainly in terms of changes he can make to the process.
  

• The Recipe Level

  The technician test mixes many glaze recipes or commercially prepared glazes hoping to find one that 'appears' to be visually suitable. When problems are encountered, a recipe is often discarded and the pursuit of another begins. On this level little is learned when a recipe does not work properly. Leaching and crazing 'consciences' tend to be underdeveloped. People trapped in this culture tend to feel quite helpless, glazes are 'mysterious' to them. Many want to have guaranteed solutions handed to them yet they are very tolerant of touchy, difficult, and expensive recipes. Many believe the 'fool proof' recipe is just around the corner.
  

• The Material Level

  The technician learns what materials do when fired and uses trial and error blending to produce glazes. He is able to achieve a degree control over the fired visual character and gains confidence. Much more is learned when glazes do not fire as expected. The physical working properties of glazes can be rationalized according to the properties of the components and adjustments made to improve application or mixing properties while maintaining fired characteristics. This approach is particularly applicable to decorative and non-functional products where the pursuit of interesting surfaces is very important. However this method falls short when it comes to producing functional surfaces and exercising greater control of diverse fired properties. Material level formulation tends to perpetuate the acceptance of results based on visual appearance only. Flux saturated glazes are examples of the products of this approach, yet they are usually unstable against chemical or mechanical attack.
  

• The Oxide Level

  The technician understands the function of oxides, the building blocks of the final fired glass. He has much greater control of many fired properties that are related directly to specific oxides or oxide systems. When problems occur this level often teaches valuable lessons that can be applied to solve current and future problems. When both the material and oxide levels are considered the technician can achieve a measure of 'material independence' (he can choose what mix of materials is best to supply a given formula of oxides). While things like blistering and crawling can be understood best by considering both the material and oxide mix of a glaze, issues like crazing and color development can only be fully grasped by consideration at this level. Each oxide has well documented contributions and interactions with others in the fired glass and proper understanding of the oxide level provides strategies for dealing with all kinds of glaze properties (i.e. hardness, surface character, crystal development, chemical stability).

We encourage you to learn about materials and ceramic calculations.

In Bound Links

• (Project) Ceramic Oxides Overview

  Ceramic formulation and adjustment technology can ...

• (Project) Glaze and Clay Body Recipes

  The industrial ceramic world generally revolves ar...

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